Bis[benzyl N′-(3-phenylprop-2-enylidene)hydrazinecarbodithioato-κ2 N′,S]zinc(II)
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چکیده
In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra-hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol-ecules are connected by weak C-H⋯S inter-molecular inter-actions into chains along the c axis. The crystal structure is further stabilized by C-H⋯π inter-actions involving the phenyl ring of the 3-phenyl-prop-2-enyl-idene unit.
منابع مشابه
Bis[benzyl N′-(3-phenylprop-2-enylidene)hydrazinecarbodithioato-κ2 N′,S]copper(II)
The Cu(II) atom of the title complex, [Cu(C(17)H(15)N(2)S(2))(2)], lies on a twofold rotation axis, and is in a distorted tetra-hedral geometry with the two bidentate N(2)S(2) Schiff bases. In the crystal structure, the mol-ecules are inter-connected into chains along the c axis by weak C-H⋯S inter-molecular inter-actions. The crystal packing is further stabilized by C-H⋯π inter-actions.
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